Dienes can be divided into three classes, depending on the relative location of the double bonds:
Cumulated dienes have the double bonds sharing a common atom as in a group of compounds called allenes.
Conjugated dienes have conjugated double bonds separated by one single bond.
Unconjugated dienes have the double bonds separated by two or more single bonds. They are usually less stable than isomeric conjugated dienes.
Compounds that contain more than two double bonds are called polyenes. Polyenes and dienes, share many of their properties.
Some dienes: A: 1,2-Propadiene, also known as allene, is the simplest cumulated diene. B: Isoprene, also known as 2-methyl-1,3-butadiene, the precursor to natural rubber. C: 1,3-Butadiene, a precursor to synthetic polymers. D: 1,5-Cyclooctadiene, an unconjugated diene (notice that each double bond is two carbons away from the other). E: Norbornadiene, a strained bicyclic and unconjugated diene. F: Dicyclopentadiene. G: Linoleic acid, a fatty acid that is required in the human diet.
Cycloadditions
An important reaction for conjugated dienes is the Diels–Alder reaction. Many specialized dienes have been developed to exploit this reactivity for the synthesis of natural products, e.g. Danishefsky’s diene.